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Gypsum-made sulfuric acid cement

Resistance to Sulfuric Acid Corrosion of Geopolymer Concrete Based …

Geopolymer binder is expected to be an optimum alternative to Portland cement due to its excellent engineering properties of high strength, acid corrosion resistance, low permeability, good chemical resistance, and excellent fire resistance. To study the sulfuric acid corrosion resistance of geopolymer concrete (GPC) with …

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The impact of original aggregate and attached mortar types …

1. Introduction. Microbial-induced concrete corrosion (MICC) is a major peril to underground structures, precipitating material degradation and curtailing the lifespan …

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Study on Concrete Properties under Acid Attacks

II. GENERAL FEATURES OF SULFURIC ACID ATTACK Sulfuric acid [H2 (SO4)] attack on concrete may be characterized by a chemical reaction between the acidic media and cement hydration products and, if soluble, the aggregate particles, results in excessive formation of gypsum (Fig. 2.1). The nature of attack of sulfuric acid on concrete is …

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Co-preparation of calcium sulfoaluminate cement and …

A life cycle assessment also showed that the co-production of calcium sulfoaluminate cement and sulfuric acid using the decomposition of industrial by …

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PHOSPHOGYPSUM: A Review of the Florida Institute of …

The idea was to use Iowa natural gypsum to produce sulphuric acid and lime, two of the most widely used industrial chemicals, and thereby create a chemical …

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Effects of sulfuric acid attack on hydrated calcined …

The paper presents experimental findings on the performance of Limestone Calcined Clay Cement (LC3) in acidic media. LC3 was made by inter-grinding a blend of 50 % clinker with ground 30 % Fired Rejected Clay Bricks (FRCB), 15 % limestone and 5 % gypsum. Compressive strength and water absorptivity of LC3 mortars were investigated …

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SVXP

which is made of sulfuric acid modified steel slag, β-hemihydrate gypsum and calcium aluminate cement. With this, the hydration rate of anhydrite-Ⅱ phosphogypsum is clearly increased and setting time shortened. The performance of self leveling mortar prepared is as per JC/T 1023-2021, with softening coefficient of 0.8. 1. …

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Materials Proceedings | Free Full-Text | Study of …

An accelerated sulfuric acid spraying test in a custom-made spraying chamber used to examine the consumption of magnesium hydroxide coating, which was applied on poly (methyl methacrylate) plates, instead …

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Method of producing sulfuric acid and hydraulic cement from gypsum

The cement clinker made from limestone carries from 0.10 percent to 2 percent S03 according to the fuel and raw materials used in making. ... Process for directly producing sulfur xide and sulfuric acid using gypsum as raw material US8623319B2 (en) * : : Xiaolin Yin ...

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Frontiers | Performance of high-belite calcium …

In addition, when the concrete made using ordinary Portland cement (OPC) is exposed to a sulfuric acid environment, the dissolution of CH occurs followed by the …

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Resistance to Sulfuric Acid Corrosion of Geopolymer Concrete …

1. Introduction. Concrete durability refers to the resistance of concrete against the action of aggressive environmental media which threaten the normal service of concrete components [].The actions of these aggressive environmental media are usually summarized as acid attack [], sulphate attack [], and chloride-induced corrosion [].In the …

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Resource utilization of Industrial gypsum and its prospect

Pointing out that industrial routes such as preparing sulphuric acid co-production cement, calcium ferrite and conversion of ammonium to sulphuric acid by industrial gypsum are feasible, which ...

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Co-preparation of calcium sulfoaluminate cement and …

To study this possibility, it is vital to determine whether IBP gypsum can be effectively decomposed to form clinker minerals in a normal manner and whether the SO …

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Sulfuric Acid from Phosphogypsum, DMC-FIPR Process

Current established technology for making sulfuric acid (H 2 SO 4) and cement clinker by-product from phosphogypsum (such as the OSW process developed by Chemie Linz, Austria) is not economic when compared with sulfur burning.It has only been applied in a few locations (Austria, China, and South Africa) where special circumstances prevail.

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Belitic Calcium Sulfoaluminate Cement Subjected to Sulfate …

Adjustments made to the sulfuric acid solution could have . ... formation of gypsum, and compressive strength, as well as the relationship among the formation of ettringite, pore structure, and ...

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The kinetics of the precipitation of gypsum, CaSO4·2H2O

Of the precipitates, calcium sulfate – crystallizing mainly in the form of gypsum, calcium sulfate dihydrate (CaSO 4 ·2H 2 O) – is one of the most common representatives, which is present (or may form) in a large variety of natural and industrial processes, such as acidic wastewater treatment, phosphonic acid production, wet flue …

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Study of magnesium hydroxide protective coating against …

An accelerated sulfuric acid spraying test in a custom-made spraying ... the formation of gypsum (i.e., the main corrosion product of concrete) during the performed tests, by X-ray Diffraction ...

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Effect of magnesium sulphate and sulphuric acid attack on …

In laboratory, the cement prepared using clinkers: ground calcined clay: low grades of limestone: gypsum in proportion as 50:30:15:5. This cement contains 53-grade OPC, which meets IS 12269–2013 [17].An X-ray fluorescence test was used to find out the material oxide constituents shown in Table 1.The specific gravity of prepared cement …

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Frontiers | Performance of high-belite calcium sulfoaluminate cement …

In addition, when the concrete made using ordinary Portland cement (OPC) is exposed to a sulfuric acid environment, the dissolution of CH occurs followed by the formation of gypsum (CaSO 4 ·2H 2 O). This process introduces further damage due to sulfate attack, i.e., expansion due to ettringite formation and subsequent cracking, as …

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Preparation and characterization of Portland cement clinker …

The experimental raw material was fly ash from Shuozhou Second Power Plant of China, and the composition of fly ash was analyzed by XRF spectral qualitative analysis combined with chemical total analysis, the result was shown in table 1.The main chemical composition in fly ash were SiO 2, Al 2 O 3, Fe 2 O 3 and CaO. The physical …

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US6613141B2

A method and apparatus for recovering calcium sulfate di-hydrate (gypsum) from a precipitation reaction between cement kiln dust and commercial, spent or waste grade sulfuric acid solution. The gypsum recovered from this process acts as a necessary functional additive for use in the production of hydraulic Portland cement. The invention …

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Effect of magnesium sulphate and sulphuric acid attack on …

The cement prepared from limestone and pozzolana showed greater resistance to sulfuric acid attack when immersed in a 3% H 2 SO 4 solution compare to OPC [11]. Compared to concrete with inert aggregates, marble concrete displayed less degradation when subjected to sulfuric acid immersion test and impact resonance tests …

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Biogenic sulfuric acid corrosion resistance of new artificial reef concrete

The biogenic sulfuric acid corrosion simulation device is schematically shown in Fig. 1, which has been modified based on the one reported in literature [18].H 2 S is produced in part 1 while part 2 conducts the biogenic sulfuric acid corrosion. H 2 S was produced by Na 2 S (0.086 M) and HCl (0.042 M). Volumetric flow of Na 2 S and HCl …

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(PDF) Effect of Temperature and Acidity of …

Effect of Temperature and Acidity of Sulfuric Acid on Concrete Properties ... As the gypsum material is 65 eroded, the concrete loses its binder and begins to spall, exposing new surfaces. ... Sulphuric acid baths 4 143 …

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Influence of polymer addition on biogenic sulfuric acid attack of concrete

A simple and reproducible microbiological simulation procedure in combination with a chemical procedure was used to test concrete for its potential resistance towards biogenic sulfuric acid.Concerning fundamental aspects of the corrosion reaction, it was shown that particularly the penetration of H 2 S inside the concrete …

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Co-preparation of calcium sulfoaluminate cement and sulfuric acid …

Industrial by-product gypsum is a waste by-product containing mostly calcium sulfate. Problems related to its storage and utilization have become a bottleneck restricting the development of various industries. The authors investigated the feasibility of co-producing calcium sulfoaluminate cement and sulfuric acid through the mass utilization of …

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The impact of original aggregate and attached mortar types …

Recycled concrete aggregate (RA) is composed of original aggregate and attached mortar, both of which are essential in determining the durability and mechanical characteristics of recycled concrete. In this investigation, the sulfuric acid resistance of geopolymer concrete (GPC) was assessed using various RA types, incorporating …

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Resistance of the composite cementitious system of ordinary …

The sulfuric acid resistance of the composite cementitious system of ordinary Portland cement (OPC)/calcium sulfoaluminate (CSA) cement is presented in this paper. Specimens were exposed to sulfuric acid solution for 70 days, and deterioration was evaluated in terms of visual appearance, mass change, and compressive strength …

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Co-preparation of calcium sulfoaluminate cement and …

The environmental impact of the co-preparation process of CSA cement and sulfuric acid using IBP gypsum decomposition was evaluated using a life cycle assessment (LCA) procedure specified in the ISO 14040 series (Simapro 9.0). The …

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Belitic calcium sulfoaluminate cement subjected to sulfate …

The degree of concrete deterioration is increased by alternate wet-dry cycles of exposure to sulfuric acid. The rate of concrete deterioration along the penetration depth of sulfuric acid could be ...

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